The competition holders kick off their new campaign to retain their crown against Juventus.
“The owner (Roman Abramovich) has never lost his ambition,” Di Matteo said.
“He always wants to win with this club and continue to drive for excellence. As long as he is at the helm his ambition to win will never diminish.”
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.