The Brazilian suffered a muscle injury against Celta Vigo that forced him off before half time.
Adriano had filled in at centre back at times for Tito Vilanova in place of the injured duo Carles Puyol and Gerard Pique.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.