The news is a blow to the French champions, who have had a poor start to the season.
Ait-Fana scored a crucial goal for Montpellier in their last Champions League game, where they picked up their first ever point in the competition against Schalke.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.
