Having trailed 2-0, Ajax rallied through Christian Eriksen and Kolbeinn Sigthorsson to draw level and force extra time.
Eriksen then turned provider for Siem de Jong to net the winner and give Ajax the best possible start to the new campaign.
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Who of Europe’s top strikers will move to England this summer?
After a dreadful start to their Bundesliga campaign, Borussia Dortmund appear to have weathered the storm after going five matches without defeat.