The Brazilian pulled a thigh muscle and had to be withdrawn in the first half.
Barcelona are now without their first choice defence, with Gerard Pique, Carles Puyol and Eric Abidal all out injured.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.