Jesus Molina was sent off for America early on, after they had fallen 1-0 behind and 2-0 down on aggregate.
However two late goals from corners, including a header from their goalkeeper, secured a remarkable comeback and America then won on penalties.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.