Djourou is likely to leave Arsenal and could replace Lucio, who is set to depart Juventus in January.
Arsenal are keen to sign a forward in the transfer window and Matri could be the ideal option having fallen out of favour in Turin.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.