Diego Simeone’s side are level on points with the Catalans after a blistering start to the season.
Real Madrid won 5-0 against Real Mallorca on Sunday, a day after Barcelona’s own 5-0 win against Rayo Vallecano.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.