Diego Simeone’s side are level on points with the Catalans after a blistering start to the season.
Real Madrid won 5-0 against Real Mallorca on Sunday, a day after Barcelona’s own 5-0 win against Rayo Vallecano.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.