Balotelli strained a muscle in the defeat to Brazil at the weekend and was to miss the Spain semi final on Thursday.
He will now miss the rest of the tournament with his AC Milan team mate Stephan el Shaarawy set to take his place.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.