It will be the third time in three seasons that the two sides have met in the competition.
Barcelona booked their spot in the semis last night with a 4-2 win against Malaga, securing a 6-4 aggregate victory.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.