The Basque outfit were 2-0 down to goals from Pedro and Leo Messi but Barcelona had Gerard Pique sent off.
That allowed the home team to fight their way back, winning late on thanks to a goal from Imanol Agirretxe in stoppage time.
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After a dreadful start to their Bundesliga campaign, Borussia Dortmund appear to have weathered the storm after going five matches without defeat.