Second placed Atletico went ahead through Radamel Falcao but Adriano equalised before Sergio Busquets put them ahead.
Two goals from Leo Messi wrapped up the win and ensured Barcelona remain clear at the top.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.