The Catalans were the better team throughout but went behind when Cristiano Ronaldo headed in a corner.
Goals from Pedro, a penalty from Leo Messi and a third from Xavi seemed to have given Vilanova a great win but Angel di Maria netted a second for Real to leave the tie on a knife edge going into the return.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.