The Sun reports that Bayern Munich are ready to offer a deal that could rise to £45million, including bonuses.
An insider told The Sun: “The performance exposed some weaknesses that Pep believes could be sorted out by bringing in Luiz.”
Luiz joined Chelsea from Benfica for £21million just two years ago.
Since returning to Stamford Bridge, Chelsea boss Jose Mourinho has insisted that Luiz is not for sale.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.