Alcantara has long been expected to join Premier League champions Manchester United, but has now instead joined the Champions League winners.
The youngster will link up with former Barcelona boss Pep Guardiola at Bayern Munich.
Bayern Munich have agreed to pay a fee of 25 million euros for the Spain Under-21 midfielder.
Thiago will have a medical in Munich in the next few days before signing a four-year contract with Bayern, the club confirmed on their website.
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The start of the 2017-18 Premier League season is just around the corner and is shaping up to be one of the most competitive yet.
As always it is the so called “big clubs” that have splashed the most cash in the transfer window so far this summer. Manchester United or City? Arsenal or Tottenham? Who are the winners and losers of the transfer window so far?