Atletico host Newell’s hoping to overturn a 2-0 deficit from the first leg in Argentina.
“It’s extremely important that the fans support us once again,” the former Ballon D’Or winner told Globo Esporte.
“This is one of the most important games, if not the most important one in the club’s history. Everyone is thinking positive, we will fight until the last minutes to get a result.”
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.