Atletico host Newell’s hoping to overturn a 2-0 deficit from the first leg in Argentina.
“It’s extremely important that the fans support us once again,” the former Ballon D’Or winner told Globo Esporte.
“This is one of the most important games, if not the most important one in the club’s history. Everyone is thinking positive, we will fight until the last minutes to get a result.”
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.