Blanc replaces Carlo Ancelotti, who asked to leave the club after winning the title last season for Real Madrid.
Paris St Germain looked at a number of options, including Andre Villas Boas and Fabio Capello, before going for Blanc.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.