Bordeaux went ahead twice in the game but were pegged back by their opponents on each occasion.
However Cheick Diabate, who had already scored, netted a second in the last minute of the match, to seal Bordeaux’ first cup win since 1987.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.