Bordeaux went ahead twice in the game but were pegged back by their opponents on each occasion.
However Cheick Diabate, who had already scored, netted a second in the last minute of the match, to seal Bordeaux’ first cup win since 1987.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.