The first goal scored at the stadium was netted by Fred, as the Fluminense striker opened the scoring early in the second half.
England turned the game around though with goals from Alex Oxlade Chamberlain and Wayne Rooney, only for Paulinho to equalise late on.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.