The first goal scored at the stadium was netted by Fred, as the Fluminense striker opened the scoring early in the second half.
England turned the game around though with goals from Alex Oxlade Chamberlain and Wayne Rooney, only for Paulinho to equalise late on.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.