Fred scored twice, Neymar got another and Dante also struck in the comprehensive victory.
It means Brazil have now won four games in a row under Luiz Felipe Scolari after a poor start under his latest reign.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.