Fred scored in the second minute of the match after a cross and Neymar struck a superb goal just before half time.
Fred scored again just after the break, before Sergio Ramos missed a penalty and Gerard Pique was sent off.
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Who of Europe’s top strikers will move to England this summer?
After a dreadful start to their Bundesliga campaign, Borussia Dortmund appear to have weathered the storm after going five matches without defeat.