Fred scored in the second minute of the match after a cross and Neymar struck a superb goal just before half time.
Fred scored again just after the break, before Sergio Ramos missed a penalty and Gerard Pique was sent off.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.