That is the highlight of the round, with other mouth watering ties including Arsenal v Bayern Munich and Shakhtar Donetsk v Borussia Dortmund.
Elsewhere, Barcelona will be favourites to beat AC Milan, Juventus likewise against Celtic and Schalke also against Galatasaray.
Paris St Germain take on Valencia and Porto face Malaga.
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Chelsea have struggled to build momentum in the opening stages of the campaign and are currently looking over their shoulders at the relegation zone.
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