That is the highlight of the round, with other mouth watering ties including Arsenal v Bayern Munich and Shakhtar Donetsk v Borussia Dortmund.
Elsewhere, Barcelona will be favourites to beat AC Milan, Juventus likewise against Celtic and Schalke also against Galatasaray.
Paris St Germain take on Valencia and Porto face Malaga.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.