They had a £22 million offer for the Tottenham playmaker turned down earlier this month, but had been hopeful he would move.
Having failed to convince the player, who is under contract, to leave his club, they have now made a huge offer for Palermo’s Argentine star.
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Who of Europe’s top strikers will move to England this summer?
After a dreadful start to their Bundesliga campaign, Borussia Dortmund appear to have weathered the storm after going five matches without defeat.