Barcelona had an opening bid for Luiz rejected on Wednesday, but the Spanish side are convinced they can sign the defender.
The Daily Mail reports that Barcelona hope Luiz’s desire to move to the Camp Nou can help sway negotiations.
“The bid? It’s lost time for them,” said Chelsea boss Mourinho.
“My advice to them is to go to the second player on their list because they are wasting their time. We don’t want to lose our best players. No chance.”
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.