The Italian scored for his new team to complete a comeback victory over Perth Glory 2-1.
The former Juventus player moved to Australia this summer after spending his entire career in Turin.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.