The former Real Madrid and Tottenham boss has signed a four-year contract with the Ukrainian side.
“It will be a new experience. I have always thought the language of football is universal,” Ramos, 56, said on his personal website.
“They have proposed a serious project to me, and personally I always find it attractive to discover new possibilities in this profession.”
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.