The two nations are expected to battle it out to win the qualifying group, but only one can qualify automatically.
“After the game, one of the two teams will be well on course for qualification,” Del Bosque said. “This is like a cup tie that needs to be overcome. There will still be 15 points to play for after this game but the double clash with France is vital.”
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.