Dortmund opened the scoring when debutant Marco Reus struck early on.
Theodor Gebre Selassie levelled with 15 minutes left for Werder, but just over five minutes later Goetze pounced to steal the points for the champions.
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The start of the 2017-18 Premier League season is just around the corner and is shaping up to be one of the most competitive yet.
As always it is the so called “big clubs” that have splashed the most cash in the transfer window so far this summer. Manchester United or City? Arsenal or Tottenham? Who are the winners and losers of the transfer window so far?