The Argentine has been on the brink of a move to Arsenal for some time, but a breakthrough appears to have been reached after a fee was agreed with Real Madrid.
Several media outlets in Argentina, Spain and England were reporting that the deal was set to be completed in the coming days.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.