The former Bayern centre back will not be able to face his former team if he fails to recover from the injury picked up against Hoffenheim on the final day of the Bundesliga season.
Dortmund are already battling to get Mario Gotze fit in time for the match next week.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.