The victory was all the more remarkable as Sampdoria had trailed 1-0 and were down to 10 men.
The Argentine schemer looks to have now blown open the title race, although the club’s main rivals could not take advantage as Inter and Fiorentina both lost.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.