Dortmund, the German champions, lost 2-1 at home to Schalke on Saturday, leaving their title defence in tatters.
“We did not play well against Schalke and there is nothing we can do to change that,” said coach Juergen Klopp. “But the match against Real Madrid remains a cool game.”
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.