Borussia Dortmund travel to Madrid after having beaten the Spanish champions at home.
“Mourinho is nice,” said Klopp, after Mourinho suggested Dortmund could win the Champions League. “Very friendly even. And a very good friend.”
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.