Liverpool are keen on the influential centre back, although Arsenal are also interested and have already bid for the player.
But Rodgers’ connection with Williams from his time in Wales may swing the deal their way.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.