Llorente is joining the Italian champions at the end of his contract with Athletic Bilbao.
“They are one of the best on the continent,” said Llorente. “They’ve shown over the last two seasons that they are the best in Italy.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.