The Spanish club were banned by UEFA for financial irregularities and delayed payments.
They will now be replaced by the next team in La Liga who qualified for next season’s Europa League and have a UEFA license, which is Sevilla.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.