Ghana overcame Niger 3-0 to comfortably secure their passage as group winners to face Cape Verde in the last eight.
Mali fought back to draw 1-1 with DR Congo to ensure their place and a meeting with hosts South Africa in the quarter finals.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.