Vilanova was forced to quit the post last week because of a relapse in his fight against throat cancer.
Martino, who guided Newell’s Old Boys to the Argentine Clausura and the semi finals of the Copa Libertadores, will take charge for the coming campaign.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.