The Argentine struck his 24th away goal of the season, a new record, and it was also the 15th away game in a row that he has scored.
Messi has not failed to score in La Liga since the opening weeks of the season.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.