Messi struck twice in the victory over Real Mallorca, to take him past the Brazilian great who scored 75 in 1958 for Santos and Brazil.
Messi is now nine behind German star Muller, who has the all time record with Bayern Munich and West Germany from 1972.
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The start of the 2017-18 Premier League season is just around the corner and is shaping up to be one of the most competitive yet.
As always it is the so called “big clubs” that have splashed the most cash in the transfer window so far this summer. Manchester United or City? Arsenal or Tottenham? Who are the winners and losers of the transfer window so far?