Messi struck twice in the victory over Real Mallorca, to take him past the Brazilian great who scored 75 in 1958 for Santos and Brazil.
Messi is now nine behind German star Muller, who has the all time record with Bayern Munich and West Germany from 1972.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.