Messi scored Barcelona’s second and third goals, following an opener from David Villa.
Vallecano pulled one back but Barcelona are still 13 points clear now and remain on course for a La Liga record points haul.
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Since Guus Hiddink arrived at the helm, Chelsea have improved considerably after a tricky start to the campaign.
Newcastle United are staring down the barrel of relegation to the Championship for the second time in the past eight years.