Messi will be absent from the team as Barcelona begin the defence of their trophy, even though he is three goals shy of Muller’s record.
“Messi’s only thinking about helping the team to win, not about personal records,” said the Barcelona coach.
“If he was thinking the other way he would have asked me to play in the Cup.”
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.