The Italian side need to avoid defeat against Borussia Dortmund in order to seal progress to the next round of the Champions League.
Hamsik suffered a foot injury during Napoli’s shock loss to Parma on Saturday.
Hamsik missed training on Sunday and will not be included in Rafa Benitez’s squad for the clash with Borussia Dortmund.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.