The Dutch won 3-2 against Germany in a thrilling game after having led 2-0, with a last minute winner.
Spain had a more straightforward 1-0 win over Russia as they look to retain their title.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.