Pedro struck twice, whilst Barcelona team mate David Villa was also on the scoresheet.
Real Madrid’s Sergio Ramos also struck before Markel Susuaeta completed the scoring.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.