Pique has been missing for most of the season with a foot injury he suffered against Spartak Moscow in September.
But he has been included in Tito Vilanova’s squad for the trip to Celtic Park, although Carles Puyol remains sidelined.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.