PSV beat Zulte Waregem 2-0 to give themselves a useful advantage in their tie, whilst Lyon beat Grasshoppers 1-0.
Zenit St Petersburg also won, 1-0 against Nordsjaelland, Steaua Bucharest beat Dinamo Tblisi 2-0 and Basel edged out Maccabi Tel Aviv 1-0.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.