Puyol underwent knee surgery last month and was thought to be out for most of the rest of the season.
But Marca report that the centre back could be a surprise inclusion for the trip to Germany.
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The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.
Five English clubs will compete in the last sixteen of the Champions League for the first time ever as Liverpool, Manchester United, Manchester City, Chelsea and Tottenham face some difficult away matches.