The draw came days after Real had won 5-0 at the same stadium against the same team.
They win 3-1 on aggregate, although Fabio Contreao and Angel di Maria were both sent off.
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Liverpool have unveiled their new home kit for next season, sticking with the hugely popular retro styling of the current shirt.
The reputation of the Premier League means it is the most popular and one of the most watched leagues in the world.