Los Blancos cruised to a 4-0 win thanks to goals from Gonzalo Higuain, Angel di Maria, Michael Essien and Luka Modric.
Mourinho is only the fifth man to reach the milestone, and it was all the sweeter as rivals Atletico Madrid lost their unbeaten run to Valencia.
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The start of the 2017-18 Premier League season is just around the corner and is shaping up to be one of the most competitive yet.
As always it is the so called “big clubs” that have splashed the most cash in the transfer window so far this summer. Manchester United or City? Arsenal or Tottenham? Who are the winners and losers of the transfer window so far?